Poly[penta-μ-aqua-μ6-methylenedisulfonato-μ5-methylenedisulfonato-tetrasodium(I)]
نویسندگان
چکیده
The title compound, [Na(4)(CH(2)O(6)S(2))(2)(H(2)O)(5)](n), was crystallized from an aqueous solution. The sodium ions are surrounded and bridged by O atoms from coordinated water mol-ecules and sulfonate ions in a three-dimensional neutral network. The crystal structure is also stabilized by an intricate system of hydrogen bonds.
منابع مشابه
Poly[μ2-aqua-diaqua(μ8-3-nitrobenzene-1,2-dicarboxylato)(μ6-3-nitrobenzene-1,2-dicarboxylato)tetrasodium]
In the title layered coordination polymer, [Na(4)(C(8)H(3)NO(6))(2)(H(2)O)(3)](n), the doubly deprotonated 3-nitro-benzene-1,2-dicarboxyl-ate ligands exhibit μ(8)- and μ(6)-coordination modes to the sodium ions, generating sheets lying parallel to (001). The coordination environments of the sodium ions are distorted octa-hedral, distorted trigonal-bipyramidal and moncapped trigonal-prismatic. O...
متن کاملPoly[[tetra-μ2-aqua-diaqua-μ6-oxalato-barium(II)] 2,4,6-trinitrophenolate monohydrate]. Corrigendum
In the paper by Hong, Song & Wu [Acta Cryst. (2007), E63, o2296], the scheme shows the wrong structure. The correct scheme is shown below and the compound name is corrected to "poly[[di-μ(2)-aqua-diaqua-hemi-μ(6)-oxalato-barium(II)] 2,4,6-trinitro-phenolate monohydrate", {[Ba(C(2)O(4))(0.5)(H(2)O)(4)]C(6)H(2)N(3)O(7)·H(2)O}(n).[This corrects the article DOI: 10.1107/S1600536807038159.].
متن کاملPoly[μ2-aqua-aqua-μ5-naphthalene-2,7-disulfonato-strontium]
In the crystal structure of the polymeric title compound, [Sr(C(10)H(6)O(6)S(2))(H(2)O)(2)](n), the naphthalene-2,7-disulfonate dianion uses one -SO(3) unit to bind to two Sr(II) cations and the other -SO(3) unit to bind to three Sr(II) cations; of the two coordinated water mol-ecules, one is monodentate to one Sr(II) cation, whereas the other bridges two Sr(II) cations. The μ(5)-bridging mode ...
متن کاملPoly[μ-aqua-diaqua(μ3-1H-benzimidazole-5-carboxylato-κ3 N 3:O,O′)(μ2-1H-benzimidazole-5-carboxylato-κ3 N 3:O:O′)-μ5-sulfato-μ4-sulfato-tricadmium]
The asymmetric unit of the title compound, [Cd(3)(C(8)H(5)N(2)O(2))(2)(SO(4))(2)(H(2)O)(3)](n), contains three Cd(II) ions, two sulfate anions, two 1H-benzimidazole-5-carboxyl-ate (H(2)bic) ligands and three coordinated water mol-ecules. One Cd(II) ion is six-coordinated and exhibits a distorted octa-hedral geometry, while the other two Cd(II) ions are seven-coordinated, displaying a distorted ...
متن کاملPoly[ethylenediaminium [di-μ-aqua-(μ6-benzene-1,2,4,5-tetracarboxylato-κ10 O 1,O 1′:O 2,O 2′:O 2′:O 4,O 4′:O 5:O 5,O 5′)dithallium(I)]]
The title compound, {(C(2)H(10)N(2))[Tl(2)(C(10)H(2)O(8))(H(2)O)(2))]}(n), was prepared using (enH(2))(2)(btc)·2H(2)O and thallium(I) nitrate (en = ethyl-enediamine and btcH(4) = benzene-1,2,4,5-tetra-carboxylic acid). The enH(2) cation and btc ligand are each located on an inversion centre. The Tl(I) atom is seven-coordinated by three btc ligands and two water mol-ecules in an irregular geomet...
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